通过孔径分布调控技术获得某领域专用活性炭材料已成为当前活性炭开发的研究热点。本项目针对国内现有有机溶剂回收专用粘胶基活性炭纤维（ACF）吸附能力和孔结构无法满足使用要求而性能优异的酚醛基ACF孔结构调控机理研究较为缺乏的现状，以碳收率较高的酚醛树脂为碳前躯体，首先攻克酚醛树脂熔融纺丝过程控制的难题，采用共混熔融纺丝技术制备出易于活化成孔的改性酚醛纤维，并通过原料-工艺-结构-性能间的关系的建立对熔融纺丝过程控制机理进行深入研究；然后综合采用活化法和聚合物混合碳化法两种孔径分布调控技术，攻克酚醛基ACF孔结构调控的难题，在酚醛基ACF内部构建大孔-介孔-微孔多级孔结构，并对其孔结构调控机理进行深入研究；最后通过工艺优化设计，定向制备出满足有机溶剂回收使用要求的高性能酚醛基ACF。旨在对酚醛基ACF孔结构调控相关理论体系进行丰富和完善的同时，进一步拓展酚醛基ACF在有机溶剂回收领域的应用。

Directed fabrication of activated carbon material for a certain field via pore size distribution control technology has become a research hotspot in the development of activated carbon. Currently, the adsorption capacity and the pore structure of the existing viscose-based activated carbon fibers (ACF) cannot meet the requirements for organic solvent recovery satisfactorily. Phenolic resin-based ACF has excellent properties, but few research has been done on its pore structure control mechanism. In consideration of current situation, phenolic resin with high carbon yield is used as the carbon precursor in this research. Firstly, the difficult process control problem for melt spinning of the phenolic resin will be overcome and modified phenolic fiber with good pore-forming property will be prepared by using blending melt spinning technology. Moreover, the process control mechanism for melt spinning of the phenolic resin will be thoroughly studied by clarifying the relationships between the raw material, the melt spinning process and the structure as well as the properties of the modified phenolic fiber. Then, the difficult pore structure control problem for phenolic resin-based ACF will be conquered through the combination of two pore size distribution control technologies, which are activation technology and polymer hybrid carbonation technology. A unique macropore-mesopore-micropore hierarchical pore structure will be established within phenolic resin-based ACF and the pore structure control mechanism will be investigated in depth. Finally, high performance phenolic resin-based ACF orienting to meet the requirements of organic solvent recovery will be prepared via process optimization. All in all, this study aims to further expand the application of phenolic resin-based ACF in the field of organic solvent recovery, while enriching and perfecting the relevant theoretical system of pore structure control for phenolic resin-based ACF.