有机无机杂化组装体不仅集合了各组分独自的性能，同时两者间的相互作用又赋予其一些独特性能而得到广泛的应用，这些独特的性能与杂化组装体中纳米粒子的空间分布有很大关系。因此，如何通过简单高效的方法实现杂化组装体中纳米粒子的精确定位成为研究人员关注的焦点之一。在之前的研究工作中，我们发现在热的驱动下可以实现杂化组装体中纳米粒子分布的动态调控，为纳米粒子的精确定位提供了一种可能。基于此我们将进一步考察高分子特性、纳米粒子特性以及两者之间相互作用在热驱动过程中对共组装体中纳米粒子分布的影响，研究各因素之间的关系，建立一种实现杂化组装体纳米粒子分布等功能定制的普适性方法。此外，光也将代替热来驱动纳米粒子运动，利用光易于控制的特点实现具有特殊纳米粒子分布的杂化功能材料（如梯度材料）的制备。该研究领域具有十分重要的理论和实际应用价值，为制备功能性的杂化材料提供新的思路。

Hybrid assemblies have been widely used not only because they combine the excellent performance of each component but also the unique properties attributed to the interaction between these components. These unique properties are highly related to the distribution of nanoparticles. Therefore, how to control the distribution of nanoparticles by an easy method has attracted many researchers. Recently, we demonstrated a facile approach to control the distribution of nanoparticles in hybrid assemblies dynamically through thermal induced diffusion. Hybrid materials with desired nanoparticle distribution (for example: gradient materials) can be obtained using this method. To fully understand the mechanism of this dynamic control, we here study the effect of parameters such as polymer properties, nanoparticle properties and the interaction between each other on the nanoparticles distribution during further treatment. Based on these investigations, we try to find out the inner relationships and establish a general method to constrict hybrid materials with desired morphology or nanoparticle distribution. This study is very important, which may provide a new way for constricting hybrid materials with fancy properties.