金属有机骨架（MOF）由于其在气体存储、分离和催化等众多领域的应用前景受到人们的广泛关注。作为一种新型配位聚合物多孔材料，其孔道能够容纳尺寸匹配的配合物分子。分子磁体作为众多配合物的一种，将其与金属有机骨架材料进行复合，得到分子基磁体修饰的金属有机骨架。不仅为磁性研究提供了新颖材料的物质基础，同时能促进磁性理论的发展。本计划拟开展“多孔分子磁体复合材料的合成和性质研究”，以改良分子磁体(自旋交叉，单分子磁体)的性质为导向，瞄准分子磁体与金属有机骨架复合材料前沿研究方向，围绕阐释孔道环境和磁稀释对分子磁体的调控机理这一主题，探索和发展新的合成方法，制备出新型分子磁体@金属有机骨架复合材料, 研究其磁性变化的机理和本质, 并进一步挖掘这些材料在信息存储和自旋器件方面的应用。

Metal Organic Frameworks (MOFs) have been attracting the interest of researchers because of their potential applications in gas storage, separation and catalysis. As a new type of coordination compounds-based porous materials, the hole size of MOFs can accommodate matching molecular complexes. As one of molecular complexes, molecule-based magnets can combine with MOFs, giving rise to new composites. The studies on the new composites should promote the development of the theory of magnetism. This programme plans to carry out the synthesis and properties of molecular magnet-based porous materials. The objectives are to obtain molecular magnets (spin crossover, single-molecule magnets) with good magnetic performance, to make clear the control mechanism of chemical pressure of the channel on magnetism, and to explore new synthetic methods for the preparation of molecular magnets@MOF composites. Finally, the applications of these materials in gas, information storage and spin devices will be investigated.