稀土(La、Pr)添加对V-4Cr-4Ti合金的辐照损伤行为的影响机理研究
批准号:
12105123
项目类别:
青年科学基金项目(C类)
资助金额:
30.0 万元
负责人:
罗凤凤
依托单位:
学科分类:
材料与器件辐照损伤
结题年份:
2024
批准年份:
2021
项目状态:
已结题
项目参与者:
罗凤凤
中文摘要
V-4Cr-4Ti合金因其具有良好的力学性能、热物理性能、低活化性以及与氚增殖剂、冷却剂具有良好的兼容性等,是聚变堆用结构材料的候选材料之一,然而较低的抗拉强度以及辐照硬化等问题,限制了其使用。国内外研究者们通过微量添加合金元素来优化V-4Cr-4Ti合金的机械性能以及耐辐照性能,然而其掺杂元素对钒合金辐照损伤的影响的机制尚不清晰,急需深入研究。本项目拟选取稀土钒合金为对象,研究稀土(La、Pr)添加对钒合金的沉淀相变化规律及其对性能的影响;通过同一系列的自离子辐照,对比性研究不同种类稀土钒合金中辐照缺陷、辐照析出以及辐照硬化行为;通过不同条件自离子辐照,研究稀土钒合金中辐照缺陷、辐照析出以及辐照硬化行为的演变规律,从而揭示稀土添加对V-4Cr-4Ti的辐照损伤行为的影响机制,以期深入理解合金元素影响聚变堆结构材料辐照损伤演化的微观机理,对推动聚变堆关键材料的发展具有重要意义。
英文摘要
V-4Cr-4Ti alloy is one of the candidate structural materials for fusion reactor because of its good mechanical properties, thermophysical properties, low activation and good compatibility with tritium breeder, coolant. However, its application is limited by its low tensile strength, radiation hardening and brittleness. National and international researchers optimize the mechanical properties and radiation resistance of V-4Cr-4Ti alloy by adding a small amount of alloying elements. However, the mechanism of the effect of doping elements on the radiation damage of V-4Cr-4Ti alloy is still unclear, which needs to be further studied. In this project, V-4Cr-4Ti-xRE alloy is selected as the object to study the precipitation phase change rule of RE addition (La, Pr) on vanadium alloy and its influence on properties; the irradiation defects, irradiation precipitation and irradiation hardening behavior of different kinds of V-4Cr-4Ti-xRE alloy are comparatively studied through the same series of self-ion irradiation; the evolution of the irradiation defects, irradiation precipitation and irradiation hardening behavior of the V-4Cr-4Ti-xRE alloy is studied through different conditions of self-ion irradiation, in order to reveal the mechanism of the influence of the RE addition on irradiation damage behavior of V-4Cr-4Ti alloy, to further understand the microscopic mechanism of the influence of alloy elements on the radiation damage evolution of fusion reactor structural materials, and it is of great significance to promote the development of key materials for fusion reactor.
V-4Cr-4Ti合金因其具有良好的力学性能、热物理性能、低活化性以及与氚增殖剂、冷却 剂具有良好的兼容性等,是聚变堆用结构材料的候选材料之一,然而较低的抗拉强度以及辐照 硬化等问题,限制了其使用。本研究通过添加低活化稀土合金元素(Y、La和Pr)来优化V-4Cr-4Ti合金的耐辐照性能。我们使用真空非自耗电弧熔炼炉制备稀土钒合金,并对其进行不同温度的热处理,研究稀土添加对钒合金晶粒尺寸、硬度以及沉淀相的影响。研究发现,添加三种稀土元素后,均能降低其晶粒尺寸,并减少V-4Cr-4Ti合金的富Ti析出相的富集区,同时在基体中形成稀土氧化物颗粒。通过对含La稀土钒合金进行He离子以及He/V双束先后离子辐照,发现1.0%稀土La的添加能明显的降低V-4Cr-4Ti合金在大剂量离子辐照下的肿胀率。而通过对含Pr稀土钒合金进行50dpaV离子辐照,发现稀土Pr添加仅降低其辐照后的硬化差值(ΔH),但由于辐照前含Pr稀土合金的硬度值偏低,因而其硬化率反而比V-4Cr-4Ti合金的更大。通过对V-4Cr-4Ti和V-4Cr-4Ti-1.0Re合金进行同条件的50dpa的V离子辐照以及He/V双束同时离子辐照,研究了其表面析出相在大剂量辐照情况下的稳定性。结果表明,钒合金中富Ti析出相在辐照下更为稳定,而稀土氧化物颗粒均会从颗粒的周围开始先发生变化。该项目对深入理解聚变堆候选材料钒合金的辐照行为以及合金元素影响聚变堆结构材料辐照损伤演化的微观机理具有重要意义。
国内基金
海外基金