Mg-Sn-Zn合金预变形缺陷作用下的沉淀相特征及相变机制研究
批准号:
52101167
项目类别:
青年科学基金项目(C类)
资助金额:
30.0 万元
负责人:
刘超强
依托单位:
学科分类:
金属结构材料与力学行为
结题年份:
2024
批准年份:
2021
项目状态:
已结题
项目参与者:
刘超强
中文摘要
轻质高强镁合金是金属结构材料领域的研究热点,调控沉淀相特征提高其强化效果是发展高强镁合金的重要思路。Mg-Sn-Zn合金是一种极具发展潜力的低成本可时效强化镁合金,研究表明,预变形可细化该合金的沉淀相,改变其形貌,提高其强化能力。然而,预变形引入的位错、孪晶界、层错对沉淀相形貌、尺寸、分布、取向关系、惯习面等特征的影响及相关的相变机制尚不明确。本项目采用多维多尺度表征、原子尺度图像定量分析、结合力学性能测试,研究Mg-Sn-Zn合金中:不同预变形缺陷作用下沉淀相上述特征的变化,阐明不同缺陷对沉淀相特征的定量影响;沉淀相在不同预变形缺陷上析出时结构和成分的演变规律及其与缺陷应变的相互作用,揭示不同缺陷上的析出相变机制;预变形缺陷作用下沉淀相引起的力学性能变化及其与位错滑移、孪生的交互作用,评价缺陷调控沉淀相的强化效果。研究成果可为利用缺陷调控镁合金中沉淀相特征,进而调控合金力学性能提供指导。
英文摘要
Lightweight and high strength magnesium alloys are the hot topic in the field of metallic structural materials. Regulating precipitate features to improve their strengthening effects is a significant method to develop high strength age-hardenable magnesium alloys. Mg-Sn-Zn alloy is a low-cost age-hardenable alloy with a great developing potential. It has been reported that pre-deformation can refine precipitates, change their morphologies and improve their strengthening effect in the alloy. However, it remains unclear that how the dislocation, twin boundary, and stacking fault introduced by pre-deformation effect the morphology, size, distribution, orientation, habit plane of the precipitate, and what the phase transformation mechanism is. This project takes the Mg-Sn-Zn alloy as the research object, utilizing multi-dimensional and multi-scale accurate characterization, quantitative analysis of atomic-scale image and mechanical property test to study the following things. First, the effect of different pre-deformation defects on the precipitate features in the alloy would be investigated carefully to clarify the quantitative effect of the different defects on the precipitate features. Then, structure and composition evolution of the precipitate on the different pre-deformation defects and the interaction of strain between precipitate and different defects would be studied to reveal the phase transformation mechanisms on these defects. Finally, the change of mechanical property of the alloy caused by the precipitate precipitation on the pre-deformation defects and the interaction between the precipitate and dislocation gliding and twinning during plastic deformation would be investigated to evaluate the strengthening effect of these precipitates. The research outcomes of this project can guide the precipitate feature modification via introducing defects and then provide a scientific guidance to improve the mechanical property of magnesium alloys.
轻质高强镁合金是金属结构材料领域的研究热点,调控沉淀相特征提高其强化效果是发展高强镁合金的重要思路。研究表明,晶格缺陷(位错、孪晶界和层错等)对时效过程中沉淀相的形貌、尺寸、分布、位相关系等特征产生重大影响,从而影响其时效硬化效果。然而,晶格缺陷影响沉淀相析出行为的机制尚不清楚。本项目以Mg-Sn-Zn合金为研究对象,系统研究了预变形+预时效和预时效和对合金时效硬化效果和沉淀相析出行为的影响,发现未经预变形(仅预时效)合金的时效硬化效果与单级时效合金相差不大,而预变形+预时效后合金的时效硬化效果可提高~40%以上,析出相的尺寸明显细化,数密度显著提升,且析出相的形貌变为短棒状或多边形状。通过精细表征发现,预变形+预时效合金具有最细沉淀相的原因是:1)预变形可向合金中引入高密度晶格缺陷,显著提高预时效过程中MgZn2和Mg3Sn相的形核率,由于MgZn2和Mg3Sn相均可作为Mg2Sn强化相的异质形核质点,从而大幅增加时效过程中Mg2Sn相的形核率;2)预时效过程中并不能完全消除预变形产生的晶格缺陷,因此,高密度的晶格缺陷也可增加Mg2Sn强化相的形核率,提高其数密度。通过本项目的研究也发现,HCP孪晶界可明显改变沉淀相的析出行为,其原因主要体现在两方面:其一,孪晶界通常可诱发溶质原子偏聚,为沉淀相的形核提供化学环境,从而促进其形核;其二,孪晶界上共格部分其特殊的结构可能类似于沉淀相的结构单元,从而有利于沉淀相结构的形成。本项目的研究成果可为利用缺陷调控镁合金中沉淀相特征,进而调控合金力学性能提供指导,也可丰富非均匀相变理论。
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批准号:2026JJ50481
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项目类别:省市级项目
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资助金额:0.0万元
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批准年份:2026
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负责人:刘超强
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依托单位:
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批准号:2022JJ40604
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项目类别:省市级项目
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资助金额:0.0万元
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批准年份:2022
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负责人:刘超强
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依托单位:
国内基金
海外基金