课题基金 / 基金详情

椭球玻璃中Gardner转变的研究

批准号:
12104495
项目类别:
青年科学基金项目(C类)
资助金额:
30.0 万元
负责人:
王锡朋
学科分类:
软凝聚态与生物物理
结题年份:
2024
批准年份:
2021
项目状态:
已结题
项目参与者:
王锡朋

项目摘要

结项摘要

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中文摘要
近来平均场理论副本对称破缺(RSB)被成功应用到结构玻璃上,并预测在深度过冷液体发生普通玻璃到Gardner相玻璃的转变,Gardner转变是类二级相变, Gardner相玻璃具有层级结构的自由能景观。RSB理论没有包含低维玻璃的情况。分子模拟显示,从准一维到三维具有硬球极限的玻璃体系依然存在Gardner相玻璃,但是与理论预言的不同,Gardner转变只是一个交叉点(crossover)。在软球体系(比如Lennard-Jones),尽管发现了被认为与Gardner物理相关的局域化缺陷,然而却没有探测到Gardner相玻璃。.硬椭球与圆球相比不同的是hypostaticity,即相互接触的配位数小于自由度的数目,违反了Maxwell力学稳定准则,导致了力和间隔分布不再具有幂律分布,此幂律行为在圆球体系被认为是临界稳定的条件。我们将运用分子模拟研究椭球的特殊性如何影响Gardner物理。
英文摘要
Up on fast cooling or compression, a liquid can undergoes glass transition with sluggish dynamics, glass is solid but its structure is similar to liquid. Understanding the nature of glass transition and glassy state is one of the most important issues. Despite the existence of many theories about the glassy state, most of them are phenomenological and tailored for specific problems. Recently, a mean field theory, i.e. replica symmetry breaking (RSB), which originates from the mean- field theory of spin glasses. has been successfully applied to structural glass: it predicts that there is a Gardner transition in the deeply supercooled liquid, at least in high dimensions (d≥6). The Gardner transition is second order-like, with diverging correlation length, susceptibility, etc., The resulting Gardner phase has hierarchical landscape of free energy and is marginal stable. Recent molecular simulation results show that even in physically accessible dimensions (i.e., from quasi-one dimension to three dimension), the Gardner phase still exists in the hard-sphere limit: the difference is that the Gardner transition in these systems just shows up as a crossover, i.e. no diverging correlation length and susceptibility, etc.. However, in soft-particle systems (e.g., Lennard Jones), the Gardner phase is absent, although localized defects are detected, which are considered to be related to the Gardner physics. At this stage, an explanation for this behavior is lacking. So the question remains to what extent, the Gardner physics scenario still holds in real systems..Amorphous packings of nonspherical particles such as ellipsoids are known to be hypostatic: The number of mechanical contacts between particles is smaller than the number of degrees of freedom, thus violating Maxwell’s mechanical stability criterion. Recent theory work reveals that hypostaticity can result in the breakdown of the power-law behavior of the force and gap distributions near the jamming point. This behavior contrasts with isostatic jamming of spherical particles. In fact, power-law behavior of the force and the gap is considered to be an essential condition for marginal stability near jamming point. Our project will investigate how the absence of two this power-law behavior will affect the Gardner physics.
本研究计划旨在深入探索椭球玻璃体系中可能涉及的Gardner转变现象,并结合理论分析与数值模拟方法对玻璃态系统在非平衡条件下的微观结构重构问题进行系统研究。研究初期,我们广泛查阅了国内外大量文献,全面掌握了椭球玻璃体系及Gardner转变的基础理论与最新进展,明确了非平衡态下能量景观重构、多极小值状态形成与局部相变之间的内在联系。但这些理论背景为整体研究提供了重要概念支持和方法指导,推动了我们在复杂体系中探索新物理现象的研究思路。. 我们用Lowe-Andersen thermostat数值模拟方法,对驱动系统中Onsager互易关系在非平衡条件下的适用性进行了严格检验。我们设置了不同驱动强度,通过大规模模拟和统计分析。模拟结果显示,即使非常大的驱动下,系统表现出Onsager互易关系依然成立。该研究为非平衡统计物理领域提供了新的理论依据,也为理解复杂体系中微观状态转换过程提供了启示。. 此外,我们还对晶体表面同素异形体湿润层的形成机制进行了深入探讨,通过理论分析与数值模拟相结合的方法,我们系统研究了界面能、晶体各向异性以及热力学驱动力在不同温度下对晶体表面结构演化的影响。研究表明,晶体表面在特定条件下会形成层次分明、形态各异的湿润层。这一发现不仅丰富了我们对晶体表面相变和多相竞争机制的认识,也为新型材料的表面改性和功能化设计提供了重要理论指导和实验基础。. 总体而言,本项目通过理论与数值模拟相结合的研究方法,深入探讨了复杂体系的能量响应和状态演化机制,为理解玻璃态系统中微观结构重构和多稳态转变问题提供了坚实的理论支撑。以第一作者基于本基金资助,在Physical Review Letters和Nature Physics上分别发表了重要论文,这不仅标志着本研究在前沿物理领域取得了显著突破,也为后续相关课题的深入开展奠定了坚实基础.
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