宋代建窑黑釉瓷的磁性和穆斯堡尔谱研究

应用磁性、穆斯堡尔谱等分析技术进行的古陶瓷学研究是现代科技考古学中比较前沿的一个课题，也是一个研究热点。建窑在我国陶瓷史上占有重要的地位，对我国后世的制瓷业产生了深远的影响，具有极高的研究价值。本项目将以建窑窑址出土的宋代黑釉建盏以及新烧黑釉盏标本为研究对象，采用X射线荧光光谱、XRD、TEM等表征建盏胎和釉的成分、微结构及形貌特征。由穆斯堡尔谱研究分析建盏胎和釉中铁离子的自旋态、价态、磁弛豫和内磁场。由磁性测量结果分析其中过度金属离子的自旋态和价态，进而分析出其磁性变化。而后采用蒙特卡罗方法模拟并用模拟退火算法拟合它的磁特性,得到磁性离子之间的朗德因子、交换耦合常数。本项目深入了解古代建盏工艺技术以及完善现代黑釉盏烧制技术提供科学依据。

The study of magnetism and Mossbauer spectrum of ancient ceramics is a relatively frontier subject in modern science and technology archaeology, and it is also a research hotspot. Jian kiln plays an important role in the history of Chinese ceramics and has a profound influence on the porcelain industry in later generations. Therefore, it has very high research value. This project will take the black glazed porcelains unearthed from the Jian Kiln site in the Song Dynasty and the newly synthesized black glazed porcelains as the research objects. The composition, microstructure and morphology of the breviscapus and the glaze were characterized by X-ray fluorescence spectroscopy, XRD and TEM. The spin state, valence state, magnetic relaxation and internal magnetic field of iron ion in breviscerus and glaze were studied and analyzed by Mossbauer spectroscopy. The spin and valence states of the excess metal ions were analyzed by magnetic results, and then the magnetic changes were analyzed. The magnetic properties were simulated by Monte Carlo method and simulated annealing algorithm to obtain the Lande factor and exchange coupling constant between magnetic ions. This project provides a scientific basis for in-depth understanding of the ancient building technology and improving the firing technology of modern black glazed lamps.