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电-湿-热耦合作用下木质电热复合材料微结构力学及电热效应失效演变机制

批准号:
32071705
项目类别:
面上项目
资助金额:
58.0 万元
负责人:
梁善庆
学科分类:
草种质资源与遗传育种
结题年份:
2024
批准年份:
2020
项目状态:
已结题
项目参与者:
梁善庆

项目摘要

结项摘要

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中文摘要
木质电热复合材料是木材、电热膜、胶黏剂经胶合形成具有通电发热的功能材料,其薄弱层为电热层。在长期电热和湿热循环作用下电热层受到破坏引起微结构力学失效,导致木质电热制品出现局部高温碳化、损伤漏电、电热效应失效现象,严重阻碍推广应用,成为木质电热复合材料亟待解决的核心问题,而电热层微结构力学及电热效应失效演变机制是其突破技术瓶颈的科学问题。本项目以电热层微结构为研究对象,采用电热性能测试系统、原位纳米力学系统、红外成像系统及纳米粘弹性测试系统等先进技术,开展电-湿-热耦合作用下电热层微结构性能及电热效应演变研究。通过电热层微结构热稳定性、物相结构、界面力学、化学组分及电热特性变化规律研究,剖析微结构力学和电热效应衰减行为特征,阐明胶合界面损伤机理,建立微结构力学衰减与整体失效内在关联模式,从而揭示木质电热复合材料微结构力学及电热效应失效演变机制,为解决木质电热制品技术瓶颈提供数据和理论支撑。
英文摘要
Wood electrothermal composite is made of wood, electrothermal film and adhesive by gluing to form electrothermal function material, and its weak layer is the electrothermal layer. Under the action of long-term electric heating and humid heat cycling, the electrothermal layer is damaged and the microstructure mechanics is damaged, resulting in localized high-temperature carbonization, electric leakage, and electrothermal effect failure of the wooden electric heating products, which seriously hinders the promotion and application. These phenomena have become the key problems to be solved urgently for wooden electric heating composites, and microstructure mechanics and electrothermal effect failure evolution are the scientific problem to solve of breaking through the technical bottleneck. Therefore, the electrothermal layer microstructure is taken as the research object in this project, the failure evolution of microstructure performance and electrothermal effect under the action of electric-moisture-thermal coupling will be investigate by electrothermal test system, infrared scanning system, nanoindentation, nanoviscoelasticity test system, and so on. By studying the thermal stability, phase structure, interface mechanics, chemical composition and electrothermal characteristics of electrothermal layer microstructure, the attenuation mechanism between microstructure mechanical and electrothermal effect will be deeply analyzed, The damage mechanism of the adhesive interface will be explained, at the same time, the internal correlation model of microstructure mechanics and composite failure also will be stablished. Thus, the microstructure mechanics and electrothermal effect failure evolution of wooden electric heating composites is revealed to provide data and theory support for solving technical bottleneck of wooden electrothermal products.
项目围绕长期电热和湿热耦合作用下木质电热复合材料存在局部高温、损伤漏电、电热效应失效等电安全技术难点。以木材为基材,碳纤维发热纸为发热元件,通过叠层热压复合工艺制备木质电热复合材料,采用电热性能测试系统、三维显微系统、计算机断层扫描、纳米压痕测试系统、界面力学测试技术等表征方法,开展了电-湿-热耦合作用下木质电热复合材料电热层微结构力学及电热效应失效演变机制系统研究,取得了如下成果:(1)研究了干湿状态下木质电热复合材料电热层的微观形貌、力学性能及电热效应等基础参量,明确了电-湿-热耦合作用对电热层的微观形貌、物相结构、化学组成以及热稳定性影响机理。(2)探明了胶黏剂与碳纤维发热纸界面、树脂与木材界面的荷载强度、弹性模量、硬度、压痕深度以及界面形貌等变化规律,阐明了电热层界面微结构力学随耦合作用的演变过程,揭示了木质电热复合材料电热层的微结构力学衰减机制。(3)明确了长期电-湿-热耦合作用下电热层的温升速率、温度不均匀度、表面温度分布、电-热辐射转换效率、热阻效应等参量的衰减和失效机制,建立了木质电热复合材料电热效应的整体失效模式。(4)研究成果在Ind Crops Prod、Colloids Surf A : Physicochem Eng Aspects、Polym Compos、复合材料学报等国内外期刊发表学术论文10篇;申请发明专利2件;发表会议论文(摘要)3篇;学术报告3次;培养研究生2名,1人晋升研究员,1人晋升硕士生导师,3人晋升副研究员,1人获评中国林科院优秀青年创新人才。(5)内置式低压电热饰面人造板制备技术入选中国科协“科创中国”平台林业领域技术应用案,并完成了木质导电发热饰面板制备技术服务,研究成果为解决木质电热复合材料的电安全技术瓶颈提供了理论支撑和技术指导。
CNTs/rGO协同构筑木纤维基电热元件及其热响应演变机制
电-湿-热耦合作用下木质电热复合材料微结构力学及电热效应失效演变机制
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