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基于电磁复合的难互溶钢/铅界面非平衡冶金结合机理及性能调控研究

批准号:
52105410
项目类别:
青年科学基金项目(C类)
资助金额:
30.0 万元
负责人:
杨川
学科分类:
成形制造
结题年份:
2024
批准年份:
2021
项目状态:
已结题
项目参与者:
杨川

项目摘要

结项摘要

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中文摘要
核工业的发展对钢/铅层状复合材料提出了长寿命服役的新要求,其难以通过胶粘、钎焊等间接连接方式实现,然而熔点差异大、难互溶的钢/铅难以通过常规工艺直接冶金结合。受到铁铅在高能球磨撞击非平衡状态下产生高度化合混合相的启发,本项目巧妙地提出利用电磁复合成形方法的瞬时局部高速冲击实现钢/铅界面高温高压非平衡态直接冶金结合的新思路,并通过初步研究验证了其可行性。然而钢/铅电磁复合界面非平衡冶金组织形成机理尚不明确,界面整体复合性能有待进一步提高,因此本项目拟系统研究钢/铅电磁复合过程弹塑性变形规律、钢铅冲击接触界面材料变形机制以及非平衡状态下界面冶金结合层形成机理,以实现对钢铅界面结合性能的调控。该研究的开展将有利于满足核工业对长寿命新型钢/铅层状复合材料的重要需求,也对其它难互溶金属体系复合材料的成形提供借鉴,具有重要的工程应用价值和科学意义。
英文摘要
With the development of nuclear industry, steel/lead laminated composite is required to have much longer service life, which is difficult to be satisfied by indirect bonding method, such as adhesive bonding and Brazing. However, the significant melting point difference and extreme poor miscibility between steel and lead result that they are difficult to be directly metallurgical bonded by conventional processes. Inspired by the appearance of iron-rich Pb/Fe phases with high degree of chemical disorder under the non-equilibrium state produced by high-energy ball milling, we propose a new idea that creating the non-equilibrium state with high temperature and high pressure in steel/lead interface by taking advantage of the high-speed local impact process during electromagnetic forming, which could lead to the direct metallurgical bonding of steel/lead. And its feasibility was verified through preliminary research. However, the formation mechanism of the non-equilibrium metallurgical microstructure in the bonding interface of steel/lead has not been clarified, and the interfacial mechanical performance of overall composite tube also needs to be further improved. Therefore, we intend to systematically study the elastic-plastic deformation mechanism of the steel/lead during electromagnetic forming process, the micro deformation mechanism of the steel/lead in the impacting interface and the formation mechanism of the interface metallurgical bonding layer under the non-equilibrium state, so as to improve the steel/lead interface bonding performance. The research will be helpful to meet the important requirement of nuclear industry for new long serve life steel/lead laminated composite, and also will provide reference for the preparation of other immiscible bi-metallic composites, which has great practical and scientific significance.
钢/铅层状复合材料作为核工业领域重要的防辐射结构材料,其兼具辐射防护与承载功能,然而受限于钢铅材料物理性能的固有差异,传统制备技术难以实现理想的界面结合,无法满足核设施长寿命服役的严苛要求,亟需开发新型制备工艺。本研究采用数值模拟与实验相结合的方法,系统探究钢铅电磁复合成形工艺对界面结合强度及微观结构的影响机制。通过有限元软件ANSYAS对电磁复合成形过程进行数值模拟,重点分析放电电压与径向间隙对复合质量的影响规律,为实验参数优化提供理论指导。模拟结果表明,外管端部在集磁器作用下最先发生变形,且放电电压与径向间隙的增大可显著提高内外管碰撞速度。基于SPH方法建立微观界面冲击模型,深入研究了界面形成机制与材料射流行为:当碰撞速度低于100m/s时,界面呈平直状且无射流产生;而当速度提升至600m/s时,大量界面射流促使结合界面转变为剪切型,实现更优的冶金结合。实验采用铅合金管与45#钢管进行电磁复合成形,通过系统测试不同工艺参数下的界面结合强度,发现存在最优工艺参数区间,其中1.6mm径向间隙与10.5kv放电电压组合可获得最大结合强度。借助扫描电镜对界面微观形貌进行表征,观察到平直状、波状及无过渡层等多种界面形态,其中波状界面与剪切变形程度密切相关。过渡区存在铁铅结合区域,可能形成过饱和固溶体。透射电镜分析进一步揭示45#钢侧晶粒显著细化,伴有大量位错与可能的孪晶结构,过渡区呈现弥散分布的纳米晶体结构,推测由金属射流撞击引发的局部高温熔融快速冷却或塑性变形导致的动态再结晶所致。本研究深入揭示了钢铅电磁复合成形工艺的物理机制,为理解难互溶金属复合材料的界面结合机理提供了重要的理论依据,丰富了材料加工领域的研究成果。研究结果为优化电磁复合成形工艺参数提供了科学指导,有助于提升复合材料质量与性能,推动材料加工技术的创新发展。
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