THE CHEMISTRY OF FUNGI .76. THE SYNTHESIS AND TRANSFORMATIONS OF 3 STEREOISOMERIC 2-(2,6-DIMETHOXYBENZOYL)-3-METHOXYCARBONYL-7-OXABICYCLO[2,2,1]HEPTANES
THE CHEMISTRY OF FUNGI .76. THE SYNTHESIS AND TRANSFORMATIONS OF 3 STEREOISOMERIC 2-(2,6-DIMETHOXYBENZOYL)-3-METHOXYCARBONYL-7-OXABICYCLO[2,2,1]HEPTANES
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DOI：
10.1039/p19800002435
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发表时间：
1980-01-01
期刊：
影响因子：
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通讯作者：
HOOPER, JW
中科院分区：
文献类型：
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作者：
BORTHWICK, AD;CURRY, DJ;HOOPER, JW
1-锂-2，6-二甲氧基苯与7-氧杂双环[2.2.1]庚烷-2 β的酸酐（10）的缩合，3. β-然后将产物酯化，得到2 β-二羧酸。（2，6-二甲氧基苯甲酰基）-3 β-甲氧羰基-7-氧杂双环[2.2.1]庚烷及其异构体。描述了这些产物的各种进一步转化。
Condensation of 1-lithio-2,6-dimethoxybenzene with the anhydride (10) of 7-oxabicyclo[2.2.1]heptane-2.beta.,3.beta.-dicarboxylic acid and subsequent esterification of the product gave 2.beta.-(2,6-dimethoxybenzoyl)-3.beta.-methoxycarbonyl-7-oxabicyclo[2.2.1]heptane and its isomer. Various further transformations of these products are described.