Catalytic reduction of molecular nitrogen in solutions

Catalytic reduction of molecular nitrogen in solutions
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DOI:
10.1023/b:rucb.0000019873.81002.60
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发表时间:
2003-12-01
影响因子:
1.7
通讯作者:
Shilov, AE
Shilov, AE
中科院分区:
化学4区
文献类型:
--
作者:
Shilov, AE

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本文综述了有关溶液固氮的报道。最佳催化剂为多核配合物。反应作为多电子过程进行,并且限制步骤涉及从还原剂的电子转移。
Reports on nitrogen fixation in solution are reviewed. The optimum catalyst is the polynuclear complex. The reaction proceeds as a multielectron process, and the limiting step involves the electron transfer from a reducing agent.