Infrared spectra and structure of acetylene on NaCl(100)

Infrared spectra and structure of acetylene on NaCl(100)
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乙炔在 NaCl(100) 上的红外光谱和结构

DOI:
10.1021/j100192a021
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发表时间:
1992
期刊:
影响因子:
--
通讯作者:
G. Ewing
G. Ewing
中科院分区:
--
文献类型:
--
作者:
S. Dunn;G. Ewing

文献摘要

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本文报道了NaCl(100)分子的C{sub 2}H{sub 2}和C{sub 2}D{sub 2}红外光谱、等温线、吸附热和相互作用能。这种非简并振动的三个峰来自静态和相关场分裂。这些光谱是由于类似于1.5层乙炔低温结晶相的双层结构。参考文献41篇,图6,2个标签。
C{sub 2}H{sub 2} and C{sub 2}D{sub 2} infrared spectra on NaCl(100), their isotherms, heats of adsorption, and interaction energies are reported in this paper. The three peaks for this nondegenerate vibration are from static- and correlation-field splittings. These spectra are due to a bilayer structure similar to 1.5 layers of the low-temperature crystalline phase of acetylene. 41 refs., 6 figs., 2 tabs.