Handbook of Physical Properties of Liquids and Gases Pure Substances and Mixtures. Third Augmented and Revised Edition. By N. B. Vargaftik, Y. K. Vinogradov, and V. S. Yargin. Begell House, Inc., New York. 1996. 1359 pp. $165.00. ISBN 1-56700-063-0.
Handbook of Physical Properties of Liquids and Gases Pure Substances and Mixtures. Third Augmented and Revised Edition. By N. B. Vargaftik, Y. K. Vinogradov, and V. S. Yargin. Begell House, Inc., New York. 1996. 1359 pp. $165.00. ISBN 1-56700-063-0.
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DOI：
10.1021/je980492j
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发表时间：
1999
影响因子：
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通讯作者：
J. Dymond
中科院分区：
文献类型：
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作者：
J. Dymond
在这本关于蒸气-气体二元扩散系数的书中，作者描述了用于测量的方法，并给出了他们为表示此类数据而开发的经验方程。本书的最后三分之二是增补，其中提供了 221 种混合物的二元扩散系数数据表，这些数据是根据“正常”压力和从 213 K 到正常沸点的温度下的广义方程计算得出的。与有限的实验值进行了比较。对于讲英语的人来说，这本书的主要建议是，它收集了各种俄语来源报告的结果，并包括作者以前未发表的测量结果。它还提供了原始论文的参考文献，其中用于计算相对扩散系数的“相似方程”应用于实验数据。然而，由于这些参考文献不易获取，遗憾的是作者没有借此机会更清楚地解释方程（2.2.7）的发展和应用。没有与已提出的二元扩散系数相关性的其他方法的结果进行比较。书中有几个错误，从第 1 页菲克第二扩散定律的方程开始。增补没有索引，如果系统以逻辑方式给出，这不会有问题，但这里，例如，“异丁醇-空气”在“辛醇空气”之后，而“异丁醇-氮气”在“丙醇-氮气”之前。本节中存在许多此类不一致之处，以及诸如“四氯溴甲烷-空气”（第 86 页）和“乙酯空气”（第 84 页）等错误。此外，由于所采用的实验方法具有不同的实验不确定性，如果在补充材料中给出实际实验方法的注释，或者最好是不确定性的估计，将会很有用。最后，应该指出的是，1980 年后的参考文献很少。约翰·H·戴蒙德 格拉斯哥大学
In this volume on vapor-gas binary diffusion coefficients, the authors describe methods that have been used for their measurement and give empirical equations that they have developed for the representation of such data. The final two-thirds of the book is the Supplement, which gives tables of binary diffusion coefficient data for 221 mixtures calculated from their generalized equation at “normal” pressure and temperatures from 213 K to the normal boiling point. A comparison is made with the somewhat limited experimental values. The main recommendation for this book for an English speaker is that it collects together the results reported in various Russian sources and includes previously unpublished measurements of the authors. It also gives references to the original papers wherein their “similitude equation” for calculating relative diffusion coefficients was applied to experimental data. However, since these references are not readily accessible, it is a matter of regret that the authors did not take the opportunity to explain more clearly the development and application of equation (2.2.7). No comparison is made with the results of other methods that have been proposed for the correlation of binary diffusion coefficients. There are several errors in the book, starting with the equation for Fick’s second diffusion law on p 1. There is no index to the Supplement, which would not be a problem if the systems had been given in a logical manner, but here, for example, “isobutyl alcohol-air” follows “octyl alcoholair” whereas “isobutyl alcohol-nitrogen” precedes “propyl alcohol-nitrogen”. There are many such inconsistencies throughout this section, together with errors such as “tetrachlorobrominemethane-air” (p 86) and “ethyl esterair” (p 84). Also, since the experimental methods employed have different experimental uncertainties, it would have been useful if a note of the actual experimental method or, preferably, an estimate of the uncertainty had been given in the Supplement. Finally, it should be noted that there are very few references post-1980. John H. Dymond University of Glasgow