Contrary logic pairs and circuits using a visually and colorimetrically detectable redox system consisting of MoO3-x nanodots and 3,3-diaminobenzidine

Contrary logic pairs and circuits using a visually and colorimetrically detectable redox system consisting of MoO3-x nanodots and 3,3-diaminobenzidine
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使用由 MoO3-x 纳米点和 3,3-二氨基联苯胺组成的视觉和比色可检测氧化还原系统的相反逻辑对和电路

DOI:
10.1007/s00604-018-3190-y
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发表时间:
2019-02-01
期刊:
影响因子:
5.7
通讯作者:
He, Yi
He, Yi
中科院分区:
化学2区
文献类型:
--
作者:
Huang, Wei;Wang, Jinhu;He, Yi

文献摘要

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在输入存在的情况下产生两个或更多信号输出的逻辑系统很少。本文提出了一种由等离子体MoO_3-x纳米点和3,3-二氨基联苯胺(DAB)组成的通用逻辑系统,用于制造视觉反逻辑对和电路。它们不需要使用昂贵的仪器,但可以直观地阅读。它是基于MoO_3-x纳米点的蓝色分散体氧化后变为无色,而无色试剂DAB被各种氧化剂氧化而产生棕色的事实。在此基础上,可以制作出YES-NOT、AND-NAND、OR-NOR、XOR-XNOR、INH-IMH、MAJ-MIN等完全相反的逻辑对和电路。各种氧化剂作为输入,吸光度作为输出。描述了一种具有一票否决功能的智能逻辑投票系统,该系统基于MAJ逻辑电路和INH逻辑门的级联,以抗坏血酸(AA)为上位抗坏血酸。由于颜色变化明显,所有的逻辑运算都可以直观地阅读。
Logic systems that yield two or more signal outputs in the presence of the input are scarce. A universal logic system consisting of plasmonic MoO3-x nanodots and 3,3-diaminobenzidine (DAB) for fabrication of visual contrary logic pairs and circuits are presented here. They do not require the use of expensive instrumentation but can be visually read. It is based on the facts that the blue dispersion of MoO3-x nanodots turns to colorless after oxidation, while the colorless reagent DAB is oxidized by various oxidants to generate a brown color. On this basis, the complete contrary logic pairs and circuits such as YES-NOT, AND-NAND, OR-NOR, XOR-XNOR, INH-IMH, and MAJ-MIN can be fabricated. Various oxidants serve as inputs, and absorbances as outputs. A smart logic voting system with one-vote deny function is also described that is based on the cascade of MAJ logic circuit and INH logic gate using ascorbic acid (AA) as the superior denier. All the logic operations can visually read due to the appearance of distinct color changes.