Synthesis of star polystyrene by radical polymerization with 1,2,4,5-tetrakis(p-tert-butylphenyl selenomethyl)benzene as a novel photoiniferter
Synthesis of star polystyrene by radical polymerization with 1,2,4,5-tetrakis(p-tert-butylphenyl selenomethyl)benzene as a novel photoiniferter
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DOI：
10.1016/s0014-3057(03)00016-8
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发表时间：
2003-07
影响因子：
6
通讯作者：
T. Kwon;Koji Takagi;H. Kunisada;Y. Yuki
中科院分区：
文献类型：
--
作者：
T. Kwon;Koji Takagi;H. Kunisada;Y. Yuki
1,2,4,5-Tetrakis(p-tert-butylphenylselenomethyl)benzene was synthesized and used as a tetrafunctional photoiniferter for the polymerization of styrene. Both the yield and the number average molecular weight (Mn) of polymers increased with reaction time and Mnlinearly increased with yield of polymer. The polymerization of styrene using this novel photoiniferter permitted formation of star-shaped polystyrene containing arylseleno groups at the chain ends, and the average degree of functionality was 3.2. Photopolymerization of styrene with end-functional star polystyrene as polymeric photoiniferter afforded polystyrene having high molecular weight.
