Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate
Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate
复制标题
DOI：
10.1039/a801377b
复制
发表时间：
1998-06-07
影响因子：
4.9
通讯作者：
Hudrlik, AM
中科院分区：
文献类型：
--
作者：
Hijji, YM;Hudrlik, PF;Hudrlik, AM
氯甲基硅烷5a经历重排反应，得到氧杂硅杂环戊烷9而不是氧杂硅杂环己烷10，表明甲基优先于芳基迁移。
Chloromethylsilane 5a undergoes a rearrangement reaction to give oxasilacyclopentane 9 rather than oxasilacyclohexane 10, indicating that the methyl group migrates in preference to the aryl group.