Solid base catalysts for the synthesis of fine chemicals
Solid base catalysts for the synthesis of fine chemicals
复制标题
DOI：
10.1016/s0021-9517(02)00120-3
复制
发表时间：
2003-05-15
影响因子：
7.3
通讯作者：
Ono, Y
中科院分区：
文献类型：
--
作者：
Ono, Y
虽然固体酸催化由于其在石油炼制和石油化工过程中的重要性而受到广泛关注，但相对较少的研究集中在碱催化上。然而，碱催化剂在精细化学合成所必需的许多反应中起着决定性的作用。固体碱催化剂在许多方面比液体碱具有许多优点。本文介绍了固体碱催化的最新进展，特别是有关催化材料和催化反应的进展。反应包括异构化、羟醛缩合、Knoevenagel缩合、Michael缩合、氧化和Si-C键形成。(C)2003年由Elsevier Science（美国）出版。
Although catalysis by solid acids has received much attention due to its importance in petroleum refining and petrochemical processes, relatively few studies have focused on catalysis by bases. Base catalysts, however, play a decisive role in a number of reactions essential for fine-chemical synthesis. Solid-base catalysts have many advantages over liquid bases in many respects. Here, recent developments in catalysis by solid bases is described, especially regarding catalytic materials and catalytic reactions. The reactions include isomerization, aldol condensation, Knoevenagel condensation, Michael condensation, oxidation, and Si-C bond formation. (C) 2003 Published by Elsevier Science (USA).