Syntheses of Dithienoarsole-containing Polymers via Suzuki-Miyaura and Sonogashira-Hagihara Coupling Reactions
Syntheses of Dithienoarsole-containing Polymers via Suzuki-Miyaura and Sonogashira-Hagihara Coupling Reactions
复制标题
通过 Suzuki-Miyaura 和 Sonogashira-Hagihara 偶联反应合成含二噻吩并苯酚的聚合物
作者：
Chieko Yamazawa;Hiroaki Imoto;K. Naka
采用两种优化的钯催化偶联反应合成了主链型二噻吩并胂（DTA）聚合物。X射线荧光光谱显示，在所获得的聚合物中没有残留的金属，这意味着DTA聚合物的孤对不含配位。发射颜色被π-共轭共聚单体广泛调谐。此外，DTA聚合物的改性通过与氯化金（I）络合来进行。
Main chain type dithienoarsole (DTA) polymers were synthesized by two kinds of optimized Pd-catalyzed coupling reactions. X-ray fluorescence spectroscopy revealed that there was no residual metal in the obtained polymers, meaning that lone pairs of the DTA polymers were free from coordination. The emission color was widely tuned by the π-conjugated comonomers. Furthermore, the modification of the DTA polymer was carried out via complexation with gold(I) chloride.
影响因子：
15
作者：
Billingsley, Kelvin;Buchwald, Stephen L.
通讯作者：
Buchwald, Stephen L.