One teflon®-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net:: sorption and catalytic properties
One teflon®-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net:: sorption and catalytic properties
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DOI：
10.1039/b415960h
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发表时间：
2005-01-01
影响因子：
4.9
通讯作者：
Gómez-Lor, B
中科院分区：
文献类型：
--
作者：
Monge, A;Snejko, N;Gómez-Lor, B
Zn（C17 H8 F6 O 4）是氟内衬纳米管有机-无机3D聚合物手性结构的第一个实例，其具有两种不同类型的隔离通道，其中一种布置有来自配体分子的CF 3-基团的双螺旋;该结构是一种新的单节点4-连接网络，其仅在弯曲配体连接中心时存在，并且该化合物表现出选择性吸附和催化手性识别性质。
Zn(C17H8F6O4) is the first example of a fluoro-lined nanotube organo-inorganic 3D polymeric chiral structure, which possesses two different types of isolated channels, one of them being laid out with a double spiral of CF3-groups from the ligand molecule; the structure is a new uninodal 4-connected net that only exists when bent ligands connect the centres, and the compound exhibits selective sorption and catalytic chiral recognition properties.