Occurrence and trends in concentrations of perfluoroalkyl substances (PFASs) in surface waters of eastern China
Occurrence and trends in concentrations of perfluoroalkyl substances (PFASs) in surface waters of eastern China
复制标题
中国东部地表水体全氟烷基物质(PFASs)浓度的存在及趋势
DOI：
10.1016/j.chemosphere.2014.08.045
复制
发表时间：
2015-01-01
期刊：
影响因子：
8.8
通讯作者：
Giesy, John P.
中科院分区：
文献类型：
--
作者：
Lu, Zhibo;Song, Luning;Giesy, John P.
2011年调查了中国东部上海、江苏、浙江三省地表水中全氟烷基物质的空间分布。共采集地表水水样39个，其中河流29条，湖泊6个，水库4个。采用高效液相色谱/负电喷雾电离-串联质谱仪(HPLC/(-)ESI-MS/MS)对PFASs进行鉴定和定量。上海市的全氟辛烷磺酸浓度高于浙江省。上海和昆山的全氟辛烷磺酸(Sigma PFASs)浓度之和在39~212ngL-1之间，而浙江省的Sigma全氟辛烷磺酸浓度在0.68~146ngL-1之间。全氟辛酸(PFOA)是上海地区流行的全氟辛酸。相比之下，全氟辛酸和全氟己酸(PFHxA)是浙江省流行的全氟辛烷磺酸。全氟辛烷磺酸(全氟辛烷磺酸)的浓度范围为
Spatial distributions of perfluoroalkyl substances (PFASs) were investigated in surface waters in Shanghai, Jiangsu and Zhejiang Provinces of eastern China during 2011. A total of 39 samples of surface waters, including 29 rivers, 6 lakes and 4 reservoirs were collected. High performance liquid chromatography/negative electrospray ionization-tandem mass spectrometry (HPLC/(-)ESI-MS/MS) was used to identify and quantify PFASs. Concentrations of PFAS were greater in Shanghai than that in Zhejiang Province. Concentrations of the sum of PFASs (Sigma PFASs) in Shanghai and Kunshan ranged from 39 to 212 ng L-1, while in Zhejiang Province, concentrations of Sigma PFASs ranged from 0.68 to 146 ng L-1. Perfluorooctanoic acid (PFOA) was the prevalent PFAS in Shanghai. In contrast, PFOA and perfluorohexanoic acid (PFHxA) were the prevalent PFASs in Zhejiang Province. Concentrations of perfluorooctane sulfonate (PFOS) ranged from