PROTON ENDOR OF CU(H2O)62+ IN MG(NH4)2(SO2)4.6H2O
PROTON ENDOR OF CU(H2O)62+ IN MG(NH4)2(SO2)4.6H2O
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DOI：
10.1080/00268977900100991
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发表时间：
1979-01-01
影响因子：
1.7
通讯作者：
HORSEWILL, AJ
中科院分区：
文献类型：
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作者：
ATHERTON, NM;HORSEWILL, AJ
用ENDOR谱测量了Mg（NH_4）_2（SO_4）_2·6H_2O单晶中Cu（H_2O）_6 ~（2+）离子在15 K时的质子超精细耦合张量。所得值在铜配合物的常规分子轨道理论的框架内进行了讨论，可以得到满意的理解。离子的几何形状与纯Cu（NH 4）2（SO 4）2.6H2O中的类似。
The proton hyperfine coupling tensors in the Cu(H2O)62+ion in Mg(NH4)2(SO4)2.6H2O single crystals at 15 K have been measured by ENDOR spectroscopy. The values obtained are discussed in the framework of conventional molecular orbital theory for copper complexes and can be understood quite satisfactorily. The geometry of the ion appears similar to that in pure Cu(NH4)2(SO4)2.6H2O.