Chiral silver amide-catalyzed enantioselective [3 + 2] cycloaddition of alpha-aminophosphonates with olefins.
Chiral silver amide-catalyzed enantioselective [3 + 2] cycloaddition of alpha-aminophosphonates with olefins.
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DOI：
10.1021/ja100101n
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发表时间：
2010-02
影响因子：
15
通讯作者：
Y. Yamashita;Xun-Xiang Guo;R. Takashita;S. Kobayashi
中科院分区：
文献类型：
--
作者：
Y. Yamashita;Xun-Xiang Guo;R. Takashita;S. Kobayashi
The first catalytic asymmetric [3 + 2] cycloadditions of Schiff bases of alpha-aminophosphonates with olefins have been developed. Chiral silver amide complexes bearing (R)-DTBM-SEGPHOS worked well as catalysts for the first time, and proline phosphonic analogues were obtained in high yields with excellent exo- and enantioselectivities.
