Electrochemical synthesis, characterization, and spectroelectrochemical evaluation of poly(para amino benzoic acid-co-4,4-diaminodiphenyl sulfone) film
Electrochemical synthesis, characterization, and spectroelectrochemical evaluation of poly(para amino benzoic acid-co-4,4-diaminodiphenyl sulfone) film
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聚(对氨基苯甲酸-co-4,4-二氨基二苯砜)薄膜的电化学合成、表征和光谱电化学评价
DOI：
10.1007/s10854-019-01192-5
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发表时间：
2019
期刊：
影响因子：
--
通讯作者：
M. Ansari
中科院分区：
文献类型：
--
作者：
Fatemeh Ganjeizadeh Rohani;A. Mohadesi;M. Ansari
一种新型聚（帕拉氨基苯甲酸-co-4，4-二氨基二苯砜），即，通过简单的电聚合工艺合成了pABA-co-DDS。采用傅里叶变换红外光谱（FTIR）对其结构进行了表征。共聚物显示不同的伏安行为，通过施加不同的DDS浓度。在所有检测的pABA：DDS比例中，1：1的比例在电极表面上提供了最合适的共聚物膜。溶解性测试表明，共聚物仅溶于温的二甲基亚砜（DMSO）中。其电导率为9.02 × 10−2S cm−1。总之，合成的新型导电共聚物是一种环境友好的物质，可用于许多领域。
A novel poly(para amino benzoic acid-co-4,4-diamino diphenyl sulfone), i.e.,pABA-co-DDS, was synthesized by simple electro-polymerization processes. Its structural properties were characterized using Fourier transform infrared (FTIR) spectroscopy. The copolymer displayed different voltammetry behaviors by applying various DDS concentrations. Among all examinedpABA:DDS ratios, the 1:1 ratio provided the most suitable copolymer film on the surface of the electrode. The solubility tests revealed that the copolymer is just soluble in warm dimethyl sulfoxide (DMSO). Its electroconductivity was obtained to be 9.02 × 10−2S cm−1. In conclusion, the synthesized novel conductive copolymer is an environmentally friendly substance that can be used in many areas.