Poly[cadmium(II)-μ4-benzene-1,3-dioxyacetato]: a two-dimensional layer cadmium(II) coordination polymer
Poly[cadmium(II)-μ4-benzene-1,3-dioxyacetato]: a two-dimensional layer cadmium(II) coordination polymer
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DOI：
10.1107/s1600536804029265
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发表时间：
2004-12
影响因子：
0.9
通讯作者：
Shan Gao;Ji‐Wei Liu;L. Huo;Hui Zhao;Jing‐Gui Zhao
中科院分区：
文献类型：
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作者：
Shan Gao;Ji‐Wei Liu;L. Huo;Hui Zhao;Jing‐Gui Zhao
在标题化合物[Cd（II）-μ4-m-phenyl dichenebis [（oxy dichenacetyl）]，[Cd（C10 H8 O 6）]n中，Cd Ⅱ原子以畸变的单帽八面体配位环境存在，其中7个O原子来自4个羧基取代基。Cd原子通过苯-1，3-二氧乙酸根二价阴离子以氧乙酸根的三齿和四齿模式桥接，形成平行于（001）的二维层状结构。
In the title compound, poly[cadmium(II)-μ4-m-phenylenebis(oxyacetato)], [Cd(C10H8O6)]n, the CdII atom exists in a distorted monocapped octahedral coordination environment with seven O atoms from four carboxylate groups. The Cd atoms are bridged by benzene-1,3-dioxyacetate dianions with tridentate and tetradentate modes of the oxyacetate groups, leading to a two-dimensional layer structure parallel to (001).