Structure of the complex of sodium chloride with ‘p,p′-methylene dianiline’

Structure of the complex of sodium chloride with ‘p,p′-methylene dianiline’
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氯化钠与‘p,p’-亚甲基二苯胺’络合物的结构

DOI:
10.1039/c29710001403
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发表时间:
1971
期刊:
Journal of The Chemical Society D: Chemical Communications
影响因子:
--
通讯作者:
P. G. Owston
P. G. Owston
中科院分区:
--
文献类型:
--
作者:
J. Jarvis;P. G. Owston

文献摘要

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在配合物[(mda)3 NaCl]中,(mda =p,p′-二氨基二苯基甲烷)每个氨基与一个Cl-形成氢键,并与一个Na+配位,Na+配位为近八面体(Na-N2·52 A),Cl-配位为近三方棱柱体(Cl-N3·44 A).
In the complex [(mda)3NaCl], (mda =p,p′-diaminodiphenylmethane) each amino-group is hydrogen-bonded to one Cl– and co-ordinated to one Na+; the co-ordination round Na+ is nearly octahedral (Na–N 2·52 A) and that round Cl– nearly trigonal prismatic (Cl–N 3·44 A).