Characterization and acetone gas sensing properties of electrospun TiO2 nanorods

Characterization and acetone gas sensing properties of electrospun TiO2 nanorods
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DOI:
10.1016/j.spmi.2015.01.022
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发表时间:
2015-05-01
影响因子:
3.1
通讯作者:
Zhu, Haibin
Zhu, Haibin
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Bian, Haiqin;Ma, Shuyi;Zhu, Haibin

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在这项工作中,通过煅烧静电纺丝 TiO2/PVP 混合棒合成了随机网络结构的二氧化钛 (TiO2) 纳米棒。研究了纳米棒的结构、光学和丙酮气体传感特性。 TiO2 纳米棒是锐钛矿和金红石结构混合的多晶。 TiO2纳米棒的直径约为500 nm。室温下的光致发光(PL)光谱测量表明,包括两个发射峰的宽发射带约为401和467 nm。该传感器对丙酮(CH3COCH)表现出高响应性、良好的重现性和选择性,在500℃下具有快速响应和恢复时间。此外,还讨论了TiO2纳米棒传感器的丙酮传感机制。 (C) 2015 Elsevier Ltd. 保留所有权利。
In this work, random network structure of titanium dioxides (TiO2) nanorods was synthesized by calcining electrospun TiO2/PVP hybrid rods. Structural, optical and acetone gas sensing properties of the nanorods were investigated. The TiO2 nanorods are polycrystalline with a mixture of anatase and rutile structures. The diameter of TiO2 nanorods is about 500 nm. The photoluminescence (PL) spectra measurement at room temperature revealed that a broad emission band including the two emission peaks are about at 401 and 467 nm. The sensor shows the high response, good reproducibility and selectivity for acetone (CH3COCH) with a fast response and recovery time at 500 degrees C. In addition, the acetone sensing mechanism of the TiO2 nanorods sensors is discussed. (C) 2015 Elsevier Ltd. All rights reserved.