HEATS OF IMMERSION. V. THE TiO2-H2O SYSTEM—VARIATIONS WITH PARTICLE SIZES AND OUTGASSING TEMPERATURE

HEATS OF IMMERSION. V. THE TiO2-H2O SYSTEM—VARIATIONS WITH PARTICLE SIZES AND OUTGASSING TEMPERATURE
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V. TiO2-H2O 体系——随颗粒尺寸和排气温度的变化

DOI:
10.1021/j100827a004
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发表时间:
1961
期刊:
The Journal of Physical Chemistry
影响因子:
--
通讯作者:
N. Hackerman
N. Hackerman
中科院分区:
--
文献类型:
--
作者:
W. Wade;N. Hackerman

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得到了金红石和金红石在水中的浸没热随粒度和出气温度的变化关系。对于比表面积在约7至250 m2/g之间变化的样品,发现两种结晶变体的浸没热随着粒度的减小而减小。G.所有样品显示出类似的浸入热随除气温度的变化,即在300-350 ℃下观察到最大值。
The heats of immersion of both anatase and rutile in water have been obtained as a function of particle size and outgassing temperature. The heats of immersion of both crystalline modifications were found to decrease with decreasing particle size for samples whose specific surface area varied from approximately 7 to 250 m.*/g. All samples showed a similar variation of immersional heat with outgassing temperature, namely, maxima were observed at 300-350.