PHOTOCHEMICAL AMINATION OF TETRACYANOBENZENE WITH ACETONITRILE IN THE PRESENCE OF ALIPHATIC AMINE

PHOTOCHEMICAL AMINATION OF TETRACYANOBENZENE WITH ACETONITRILE IN THE PRESENCE OF ALIPHATIC AMINE
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脂肪胺存在下四氰基苯与乙腈的光化学胺化

DOI：
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发表时间：
1986
期刊：
影响因子：
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通讯作者：
M. Ohashi
M. Ohashi
中科院分区：
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文献类型：
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作者：
S. Yamada;Y. Nakagawa;O. Watabiki;Shin Suzuki;M. Ohashi

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在三乙胺存在下，二氰二烯和二氰二烯在乙腈中辐照主要产生取代产物和还原产物，而1,2,4,5-四氰苯在n -甲基吡咯烷或尼古丁存在下的光化学反应产生胺化产物三氰苯胺和取代产物。
Irradiation of dicyanoxylenes and dicyanodurene in acetonitrile in the presence of triethylamine gave mainly substitution and reduction products respectively, whereas a photochemical reaction of 1,2,4,5-tetracyanobenzene in the presence of N-methylpyrrolidine or nicotine gave tricyanoaniline, an amination product, as well as substitution products.