Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReOx–Pd/SiO2 catalyst
Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReOx–Pd/SiO2 catalyst
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DOI：
10.1039/c2cy20302b
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发表时间：
2012-10
影响因子：
5
通讯作者：
Y. Takeda;Y. Nakagawa;K. Tomishige
中科院分区：
文献类型：
--
作者：
Y. Takeda;Y. Nakagawa;K. Tomishige
利用ReOx-Pd /SiO2催化脂肪酸直接加氢，以高收率（>92%）合成了高级脂肪醇。ReOx - Pd/SiO2的高催化性能是由ReOx和Pd的协同作用产生的。羧酸对醇的优先吸附阻止了醇对烷烃的过度反应。
Higher fatty alcohols were synthesized in high yield (>92%) by direct hydrogenation of fatty acids catalyzed by ReOx–Pd/SiO2. High catalytic performance of ReOx–Pd/SiO2 can be generated by the synergy between ReOx and Pd. Preferential adsorption of the carboxylic acid to alcohols prohibited the overreaction of alcohols to alkanes.