A Fused Benzocyclooctene Ring System via an Aromatic Cope Rearrangement: Thermal Reactions of trans-1-Aryl-2-ethenylcyclobutanecarbonitriles
A Fused Benzocyclooctene Ring System via an Aromatic Cope Rearrangement: Thermal Reactions of trans-1-Aryl-2-ethenylcyclobutanecarbonitriles
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DOI：
10.1002/hlca.201200352
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发表时间：
2013-07-01
影响因子：
1.8
通讯作者：
Angel Maldonado, Luis
中科院分区：
文献类型：
--
作者：
Gustavo Avila-Zarraga, Jose;Vazquez-Sanchez, Adrian;Angel Maldonado, Luis
报道了反式-1-芳基-2-乙烯基环丁腈芳香族Cope重排的结果（方案）。本文还描述了利用这种重排来构造熔融苯并环烯环体系，并对有利于这种转变的电子要求进行了初步研究。
The results of an aromatic Cope rearrangement of a trans-1-aryl-2-ethenylcyclobutanecarbonitrile are reported (Scheme). The use of this rearrangement for the construction of the fused benzocyclooctene ring system and a preliminary study of the electronic requirements to favor such a transformation are also described.