THE EFFECTS OF MOLECULAR ANIONS ON THE CHEMISTRY OF DARK CLOUDS

THE EFFECTS OF MOLECULAR ANIONS ON THE CHEMISTRY OF DARK CLOUDS
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分子阴离子对暗云化学的影响

DOI:
10.1088/0004-637x/700/1/752
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发表时间:
2009
期刊:
The Astrophysical Journal
影响因子:
--
通讯作者:
T. Millar
T. Millar
中科院分区:
--
文献类型:
--
作者:
C. Walsh;N. Harada;E. Herbst;T. Millar

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We have investigated the role of molecular anion chemistry in pseudo-time-dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement between model results and observations of molecular abundances in Taurus molecular cloud 1 (TMC-1 (CP)). More importantly, with the inclusion of anions, we see an enhanced production efficiency of unsaturated carbon-chain neutral molecules, especially in the longer members of the families CnH, CnH2, and HCnN. The use of carbon-rich elemental abundances in models of TMC-1 (CP) with anion chemistry worsens the agreement with observations compared with model results obtained in the absence of anions.
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DOI: --
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