Optical spectra of Ln3+(Nd3+, Sm3+, Dy3+, Ho3+, Er3+)-doped Y3GaO6

Optical spectra of Ln3+(Nd3+, Sm3+, Dy3+, Ho3+, Er3+)-doped Y3GaO6
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DOI:
10.1016/j.jlumin.2004.06.005
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发表时间:
2005
影响因子:
3.6
通讯作者:
F. S. Liu;Qiutian Liu;Junjun Liang;J. Luo;L. Yang;G. Song;Y. Zhang;Lingxuan Wang;J. Yao-
F. S. Liu;Qiutian Liu;Junjun Liang;J. Luo;L. Yang;G. Song;Y. Zhang;Lingxuan Wang;J. Yao-
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
F. S. Liu;Qiutian Liu;Junjun Liang;J. Luo;L. Yang;G. Song;Y. Zhang;Lingxuan Wang;J. Yao-

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采用固相反应法制备了Ln 3+(Ln=Nd,Sm,Eu,Gd,Dy,Ho,Er)掺杂的Y3 GaO 6化合物,测量了它们的吸收光谱、光致发光光谱、激发光谱和时间分辨光谱。X射线粉末衍射结果表明:(Y_(0.96)Ln_(0.04))_3Ga_(O_6)的晶格常数随着三价Ln ~(3+)离子半径的减小而减小,表明Ln ~(3+)离子取代了Y ~(3+)离子进入晶格。光谱分析表明,在紫外-可见光区有明显的吸收。在可见光和红外区的强发射表明Y3 GaO 6是一种适合于掺稀土激光晶体和荧光粉的基质材料。
Ln3+(Ln=Nd, Sm, Eu, Gd, Dy, Ho, Er)-doped Y3GaO6compounds were prepared by solid-state reaction, and their optical spectra such as absorption, photoluminescence, excitation and time-resolved spectra have been measured for Ln=Nd, Sm, Dy, Ho, Er. X-ray powder diffraction shows that the lattice parameters of the compounds (Y0.96Ln0.04)3GaO6decrease with the decrease of the radii of trivalent Ln3+ions, indicating that Ln3+ions have substituted for Y3+ions in the lattice. Optical spectra show that there are obvious absorptions at ultraviolet to visible region. The strong emissions in visible and infra-red region show that Y3GaO6is a suitable host for rare-earth-doped laser crystal and phosphor materials.