A study of the photodeposition over Ti/TiO2 electrode for electrochemical detection of heavy metal ions

A study of the photodeposition over Ti/TiO2 electrode for electrochemical detection of heavy metal ions
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Ti/TiO2电极光沉积电化学检测重金属离子的研究

DOI:
10.1016/j.elecom.2015.04.015
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发表时间:
2015-08-01
影响因子:
5.4
通讯作者:
Zhang, Xiufang
Zhang, Xiufang
中科院分区:
工程技术3区
文献类型:
--
作者:
Ma, Hongchao;An, Rui;Zhang, Xiufang

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本文报道了在紫外光照射下,由于金属离子在电极表面的光沉积作用,Ti/TiO 2电极对痕量重金属离子(如Cu ~(2+)、Pb ~(2+)和Cd ~(2+))的测定灵敏度显著提高。Ti/TiO 2电极对重金属离子的灵敏度可以选择性地提高,这是由于重金属离子的电位与TiO 2导带位置相匹配。(C)2015年由Elsevier B. V.出版
Here we reported that UV light irradiation can significantly enhance sensitivity of Ti/TiO2 electrode for determination of trace heavy metal ions (such as Cu2+, Pb2+ and Cd2+) owing to the photodeposition of metal ions on the surface of electrodes. The sensitivity of heavy metal ions can be selectively enhanced over the Ti/TiO2 electrode, which is attributed to matching between potential of heavy metal ions and the position of the conduction band of TiO2. (C) 2015 Published by Elsevier B.V.