THE INFRARED-EMISSION SPECTRUM OF GAS-PHASE C60 (BUCKMINSTERFULLERENE)

THE INFRARED-EMISSION SPECTRUM OF GAS-PHASE C60 (BUCKMINSTERFULLERENE)
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DOI:
10.1016/0009-2614(91)90245-5
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发表时间:
1991-02-01
影响因子:
2.8
通讯作者:
HUFFMAN, DR
HUFFMAN, DR
中科院分区:
化学4区
文献类型:
--
作者:
FRUM, CI;ENGLEMAN, R;HUFFMAN, DR

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利用基特峰国家太阳观测台傅立叶变换光谱仪对C60的发射气相红外光谱进行了观测。在527.1、570.3、1169.1和1406.9 cm-1处发现了C60分子的条带。附加的发射特征暂定为C70或C60的组合波段。在1010.2 cm-1处观测到一个新的强发射,属于一个未知分子。这些特征都不能与迄今为止在天文来源中观测到的任何强发射带联系起来。
The gas-phase infrared spectrum of C60 has been observed in emission with the National Solar Observatory Fourier transform spectrometer at Kitt Peak. Bands attributable to the C60 molecule are found at 527.1, 570.3, 1169.1 and 1406.9 cm-1. Additional emission features are tentatively assigned to C70 or combination bands of C60. A new, strong emission is observed at 1010.2 cm-1 belonging to an unknown molecule. None of these features can be associated with any of the strong emission bands observed so far in astronomical sources.