Supramolecular architectures built of blimidazole complexes and sulfate or nitrate anions

Supramolecular architectures built of blimidazole complexes and sulfate or nitrate anions
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DOI:
10.1016/j.poly.2005.12.031
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发表时间:
2006-07-10
期刊:
影响因子:
2.6
通讯作者:
Xu, Li
Xu, Li
中科院分区:
化学3区
文献类型:
--
作者:
Sang, Rul-Li;Xu, Li

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通过 M2+-H(2)biim 片段(M = Zn、Cd 和 Cu)和无机抗衡阴离子(硫酸根或硝酸根)之间的电荷辅助氢键构建了四种新的超分子结构。已发现II型(R-2(1)(8))和III型(R-2(2)(9))氢键在其晶体结构中占主导地位。 2. (c) 2006 Elsevier Ltd. 保留所有权利。
Four new supramolecular architectures constructed via charge-assisted hydrogen bonds between M2+-H(2)biim fragments (M = Zn, Cd, and Cu) and inorganic counter-anions (sulfate or nitrate) have been established. Type II (R-2(1)(8)) and III (R-2(2) (9)) hydrogen bonds have been found to dominate their crystal structure fori-nation. An unusual four-membered water hexamer has been found in 2. (c) 2006 Elsevier Ltd. All rights reserved.