Anodic stripping voltammetry at hydrodynamic mercury thin film electrodes. Numerical simulation of stripping peaks for reversible processes at uniformly accessible electrodes
Anodic stripping voltammetry at hydrodynamic mercury thin film electrodes. Numerical simulation of stripping peaks for reversible processes at uniformly accessible electrodes
复制标题
流体动力汞薄膜电极的阳极溶出伏安法。
DOI：
10.1002/elan.1140091007
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发表时间：
1997
期刊：
影响因子：
3
通讯作者：
R. Compton
中科院分区：
文献类型：
--
作者：
J. C. Ball;R. Compton
采用时间依赖的倒隐式方法模拟了电化学可逆体系中汞薄膜水动力电极直流（线性扫描）阳极溶出伏安法中溶出峰的形状和位置。在旋转圆盘系统的情况下，假设扩散层厚度是均匀的和实验可控的，对峰电位和峰形状的影响是量化的，并指出了对流条件下阳极溶出伏安法的含义。
The time dependent backwards implicit method is used to simulate the shape and position of the stripping peaks in DC (linear scan) anodic stripping voltammetry at mercury thin film hydrodynamic electrodes for electrochemically reversible systems. The effect of variable diffusion layer thickness, assumed uniform and experimentally controllable in the case of rotating disk systems, in influencing both the peak potential and peak shape, is quantified and the implications for anodic stripping voltammetry under convective conditions noted.