Oxide-based inorganic/organic and nanoporous spherical particles: synthesis and functional properties.
Oxide-based inorganic/organic and nanoporous spherical particles: synthesis and functional properties.
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DOI：
10.1088/1468-6996/14/2/023002
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发表时间：
2013-04
影响因子：
5.5
通讯作者：
Hanagata N
中科院分区：
文献类型：
--
作者：
Shiba K;Tagaya M;Tilley RD;Hanagata N
本文综述了近年来氧化物基和杂原子掺杂粒子的制备进展。表面活性剂模板化的氧化物颗粒，如二氧化硅和二氧化钛，是各种潜在应用的可能候选者，如吸附剂、光催化剂、光电和生物材料。我们重点介绍了单元素的纳米多孔氧化物，如硅或钛，以及那些含有多种元素的纳米多孔氧化物，它们表现出单个成分无法实现的特性。虽然多组分纳米多孔氧化物具有许多吸引人的功能，但由于其组成/结构的复杂性，其性质的起源很难确定。具有明确大小和形状的粒子是定量和详细讨论粒子独特复杂性质的关键。从这个角度出发，我们综述了有机分子官能化或杂原子掺杂氧化物粒子的合成技术，粒子的物理化学性质及其作为复杂系统光功能应用的可能性。
This paper reviews the recent progress in the preparation of oxide-based and heteroatom-doped particles. Surfactant-templated oxide particles, e.g. silica and titania, are possible candidates for various potential applications such as adsorbents, photocatalysts, and optoelectronic and biological materials. We highlight nanoporous oxides of one element, such as silicon or titanium, and those containing multiple elements, which exhibit properties that are not achieved with individual components. Although the multicomponent nanoporous oxides possess a number of attractive functions, the origin of their properties is hard to determine due to compositional/structural complexity. Particles with a well-defined size and shape are keys for a quantitative and detailed discussion on the unique complex properties of the particles. From this viewpoint, we review the synthesis techniques of the oxide particles, which are functionalized with organic molecules or doped with heteroatoms, the physicochemical properties of the particles and the possibilities for their photofunctional applications as complex systems.
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DOI：
10.1016/s0927-6513(97)00079-5
发表时间：
1997-12-01
期刊：
MICROPOROUS MATERIALS
影响因子：
--
作者：
Chen, LY;Jaenicke, S;Chuah, GK
通讯作者：
Chuah, GK
影响因子：
15
作者：
BECK, JS;VARTULI, JC;SCHLENKER, JL
通讯作者：
SCHLENKER, JL
影响因子：
29.4
作者：
Grun, M;Lauer, I;Unger, KK
通讯作者：
Unger, KK
影响因子：
17.1
作者：
Hartono, Sandy B.;Gu, Wenyi;Qiao, Shi Zhang
通讯作者：
Qiao, Shi Zhang
影响因子：
9.9
作者：
Araujo, AS;Jaroniec, M
通讯作者：
Jaroniec, M