Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from CoII Nodes and a Pyridylhydrazone Derivative
Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from CoII Nodes and a Pyridylhydrazone Derivative
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由 CoII 节点和吡啶腙衍生物构建的二维配位聚合物中的单离子磁体行为
DOI：
10.1021/acs.inorgchem.5b01651
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发表时间：
2015-09-21
影响因子：
4.6
通讯作者：
Hu, Qilin
中科院分区：
文献类型：
--
作者：
Liu, Xiangyu;Sun, Lin;Hu, Qilin
合成了一种新型的二维配位聚合物[Co（ppad）（2）]（n）（1）。化合物1的交流/直流磁研究表明，空间分离的高自旋Co-II离子作为单离子磁体（西姆斯）。本工作代表了第一种情况下的二维钴-II-基于SIM组成的单组分有机间隔。
A novel two-dimensional (2D) coordination polymer, [Co(ppad)(2)](n) (1), resulted from the assembly of Co-II ions based on a versatile ligand termed N-3-(3-p-yridoyl)-3-pyridinecarboxamidrazone. Alternating/direct-current magnetic studies of compound 1 indicate that the spatially separated high-spin Co-II ions act as single-ion magnets (SIMs). The present work represents the first case of a 2D Co-II-based SIM composed of a monocomponent organic spacer.