Resolution and circular dichroism of an asymmetrically cage-opened [60]fullerene derivative
Resolution and circular dichroism of an asymmetrically cage-opened [60]fullerene derivative
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DOI：
10.1039/a707274k
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发表时间：
1998-01-21
影响因子：
4.9
通讯作者：
Wudl, F
中科院分区：
文献类型：
--
作者：
Hummelen, JC;Keshavarz-K, M;Wudl, F
第一个笼型固有不对称 C-60 衍生物的对映体，即 N-MEM (MEM = 2-甲氧基乙氧基甲基)酮内酰胺 1，已通过 HPLC 分离，并将其手性光学性质与从不对称或由于手性附加物导致不对称的 C-60 衍生物获得的数据进行了比较。
The enantiomers of the first cagewise inherently asymmetric C-60 derivative, i.e. N-MEM (MEM = 2-methoxyethoxy-methyl) keto lactam 1, have been separated by HPLC and their chiroptical properties compared with data obtained from C-60 derivatives that are dissymmetric or asymmetric due to chiral addends.