Gram-scale free radical polymerization of an azaborine vinyl monomer
Gram-scale free radical polymerization of an azaborine vinyl monomer
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DOI：
10.1039/c7cc02300f
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发表时间：
2017-07-07
影响因子：
4.9
通讯作者：
Klausen, Rebekka S.
中科院分区：
文献类型：
--
作者：
van de Wouw, Heidi L.;Lee, Jae Young;Klausen, Rebekka S.
报道了一种新型氮杂硼基乙烯基单体的克级聚合反应。我们描述了一种高效高产的b -乙烯基-2,1-硼氮杂萘合成方法。用异核磁共振和吸光度法对2-乙烯基萘的均聚物和共聚物进行了表征。
The gram-scale polymerization of a novel azaborine vinyl monomer is reported. We describe an efficient and high-yielding synthesis of B-vinyl-2,1-borazanaphthalene. Homopolymers and co-polymers with 2-vinylnaphthalene are characterized by heteronuclear NMR and absorbance spectroscopy.