Constituents of Lepidium meyenii 'maca'
Constituents of Lepidium meyenii 'maca'
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DOI：
10.1016/s0031-9422(01)00395-8
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发表时间：
2002-01-01
期刊：
影响因子：
3.8
通讯作者：
Khan, IA
中科院分区：
文献类型：
--
作者：
Muhammad, I;Zhao, JP;Khan, IA
麻黄的块茎中含有1，2-二氢-N-羟基吡啶的苯基化衍生物，称为马卡里定，以及苯基烷基酰胺、N-苄基-5-氧代-6E、8E-十八碳二烯胺和AT-苄基十六烷基酰胺，以及开环酮基酸，5-氧代-6E，8E-十八碳二烯酸。化合物的结构鉴定主要基于一维和二维核磁共振波谱分析，包括H-1-H-1COSY，H-1-C-13 HMQC，H-1-C-13 HMBC和H-1-H-1 NOESY实验，以及从H-1-N-15核磁共振HMBC关联马卡利定和N-苄基十六胺。(C)2002年由爱思唯尔科学有限公司出版。
The tubers of Lepidium meyenii contain the benzylated derivative of 1,2-dihydro-N-hydroxypyridine, named macaridine, together with the benzylated alkamides (macamides), N-benzyl-5-oxo-6E,8E-octadecadienamide and AT-benzylhexadecanamide, as well as the acyclic keto acid, 5-oxo-6E,8E-octadecadienoic acid. The structure elucidation of the isolated Compounds was based primarily on 1D and 2D NMR spectroscopic analyses, including H-1-H-1 COSY, H-1-C-13 HMQC, H-1-C-13 HMBC and H-1-H-1 NOESY experiments, as well as from H-1-N-15 NMR HMBC correlations for macaridine and N-benzylhexadecanamide. (C) 2002 Published by Elsevier Science Ltd.