Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers.
Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers.
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DOI：
10.1002/anie.201700271
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发表时间：
2017-06-06
期刊：
影响因子：
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通讯作者：
Mateo-Alonso A
中科院分区：
文献类型：
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作者：
Marco AB;Cortizo-Lacalle D;Perez-Miqueo I;Valenti G;Boni A;Plas J;Strutyński K;De Feyter S;Paolucci F;Montes M;Khlobystov AN;Melle-Franco M;Mateo-Alonso A
扭曲的二维芳香骨架是通过用庞大的刚性取代基填充节点而制备的。高度扭曲的芳香骨架与交替的面外取代基导致层间相互作用减少，有利于有机介质中单个层的剥离和分散。
Twisted two‐dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out‐of‐plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.