A modular and efficient synthesis of functional titanocenes.
A modular and efficient synthesis of functional titanocenes.
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DOI：
10.1021/ja054185r
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发表时间：
2005-07
影响因子：
15
通讯作者：
A. Gansäuer;D. Franke;T. Lauterbach;M. Nieger
中科院分区：
文献类型：
--
作者：
A. Gansäuer;D. Franke;T. Lauterbach;M. Nieger
描述了以构建块为特征的功能性二茂钛的模块化合成。该方法可以直接获得大量结构多样的二茂钛，这些二茂钛与催化、结构研究和生物无机化学相关。引入的官能团包括氨基酸、糖和荧光标记，它们以酯和酰胺的形式连接到环戊二烯基配体上。
A modular synthesis of functional titanocenes featuring building blocks is described. The approach allows straightforward access to large numbers of structurally diverse titanocenes that are pertinent for catalysis, structural studies, and bioinorganic chemistry. Among the functional groups introduced are amino acids, sugars, and fluorescence labels that are attached to the cyclopentadienyl ligand as esters and amides.