Nanotransfer Printing Using Plasma Etched Silicon Stamps and Mediated by in Situ Deposited Fluoropolymer

Nanotransfer Printing Using Plasma Etched Silicon Stamps and Mediated by in Situ Deposited Fluoropolymer
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DOI:
10.1021/ja201497a
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发表时间:
2011-05-25
影响因子:
15
通讯作者:
Sepaniak, Michael J.
Sepaniak, Michael J.
中科院分区:
化学1区
文献类型:
--
作者:
Bhandari, Deepak;Kravchenko, Ivan I.;Sepaniak, Michael J.

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本文描述了一种简单的方法,该方法使用八氟环丁烷(OFCB)聚合物薄膜进行高效的纳米级转印(nTP)。OFCB的等离子体聚合产生了一种类似聚四氟乙烯的含氟聚合物,其牢固地粘附并保形地覆盖3-D无机印模。纳米级硅特征上原位沉积的OFCB聚合物的固有低表面能被证明是一种独特的纳米复合材料印模,用于制造各种测试结构,其nTP特征分辨率提高到低于100 nm。
This communication describes a simple method that uses a thin film of octafluorocyclobutane (OFCB) polymer for efficient nanoscale transfer printing (nTP). Plasma polymerization of OFCB produces a Teflon-like fluoropolymer which strongly adheres and conformally covers a 3-D inorganic stamp. The inherently low surface energy of in situ deposited OFCB polymer on nanoscale silicon features is demonstrated as a unique nanocomposite stamp to fabricate various test structures with improved nTP feature resolution down to sub-100 nm.