The biosynthesis of bisorbicillinoids: evidence for a biosynthetic route from bisorbicillinol to bisorbibutenolide and bisorbicillinolide
The biosynthesis of bisorbicillinoids: evidence for a biosynthetic route from bisorbicillinol to bisorbibutenolide and bisorbicillinolide
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DOI：
10.1039/b007181l
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发表时间：
2001-01-01
影响因子：
4.9
通讯作者：
Hirota, A
中科院分区：
文献类型：
--
作者：
Abe, N;Yamamoto, K;Hirota, A
木霉菌生物合成标记乙酸钠与双球菌素的结合。USF-2690表明双球菌素是由12个醋酸酯单位衍生而来的。利用该菌株洗涤的菌丝体成功地将标记的双球菌素转化为双球菌素内酯和双球菌素内酯，表明存在从双球菌素到双球菌素内酯和从双球菌素到双球菌素内酯的生物合成途径。
Biosynthetic incorporation of labelled sodium acetates into bisorbicillinol in Trichoderma sp. USF-2690 suggests that bisorbicillinol is derived from 12 acetate units. Successful bioconversion of the labelled bisorbicillinols to bisorbibutenolides (bislongiquinolides) and bisorbicillinolides using the washed mycelium of the strain suggests that there are biosynthetic routes from bisorbicillinol to bisorbibutenolide and from bisorbicillinol to bisorbicillinolide.