Surface Area Control and Photocatalytic Activity of Conjugated Microporous Poly(benzothiadiazole) Networks
Surface Area Control and Photocatalytic Activity of Conjugated Microporous Poly(benzothiadiazole) Networks
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DOI：
10.1002/anie.201207163
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发表时间：
2013-01-01
影响因子：
16.6
通讯作者：
Vilela, Filipe
中科院分区：
文献类型：
--
作者：
Zhang, Kai;Kopetzki, Daniel;Vilela, Filipe
在二氧化硅纳米粒子作为模板剂的存在下，通过Sonogashira-Hagihara交叉偶联反应制备了具有可控比表面积的共轭微孔聚合物（CMP）。CMP在连续流合成中作为非均相光敏剂用于产生单线态氧（见图）。
Conjugated microporous polymers (CMPs) with controlled specific surface area have been prepared through Sonogashira–Hagihara cross‐coupling reactions in the presence of silica nanoparticles as templating agents. The CMPs act as heterogeneous photosensitizers for producing singlet oxygen in a continuous flow synthesis (see picture).