Mild Mn(OAc)3-Mediated Aerobic Oxidative Decarboxylative Coupling of Arylboronic Acids and Arylpropiolic Acids: Direct Access to Diaryl 1,2-Diketones
Mild Mn(OAc)3-Mediated Aerobic Oxidative Decarboxylative Coupling of Arylboronic Acids and Arylpropiolic Acids: Direct Access to Diaryl 1,2-Diketones
复制标题
温和的 Mn(OAc)(3) 介导的芳基硼酸和芳基丙炔酸的有氧氧化脱羧偶联：直接获得二芳基 1,2-二酮
DOI：
10.1021/acs.orglett.5b01265
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发表时间：
2015-06-19
期刊：
影响因子：
5.2
通讯作者：
Wang, Honggen
中科院分区：
文献类型：
--
作者：
Lv, Wen-Xin;Zeng, Yao-Fu;Wang, Honggen
A simple and efficient method for the synthesis of diaryl 1,2-diketones has been developed. The reaction represents the first example of diaryl 1,2-diketones that are synthesized directly from arylboronic acids and arylpropiolic acids by a radical pathway in moderate to good yields. This reaction proceeds under mild reaction conditions and with good tolerance of a variety of functional groups. Preliminary mechanistic studies were conducted.
