Preparation of multinuclear microparticles using a polymerization in emulsion process
Preparation of multinuclear microparticles using a polymerization in emulsion process
复制标题
DOI：
10.1002/app.27283
复制
发表时间：
2008-02
影响因子：
3
通讯作者：
F. Salaün;É. Devaux;S. Bourbigot;P. Rumeau
中科院分区：
文献类型：
--
作者：
F. Salaün;É. Devaux;S. Bourbigot;P. Rumeau
建立了一种新的微胶囊化方法，即用氨基树脂包埋石蜡中微球和亚微米级小微球。这些多核微粒是通过乳液聚合制备的，并通过扫描电子显微镜和界面张力测量进行了表征。该方法基于Torza和Mason方法之后的几种乳液混合，其中我们将凝聚与常规界面反应的特征和原位聚合随后水包油包水乳液相结合。微胶囊的内相由石蜡和聚（乙烯）醇/水合盐微球的混合物通过亚甲基二异氰酸酯交联。的封装机制是基于液/固-液分离的methodolmelamines，并将在本研究中描述，以解释表面形态。© 2007 Wiley Periodicals，Inc.应用聚合物科学杂志，2008年
A new microencapsulation method, in which a paraffin medium and small sub-micron spheres were encapsulated by an amino resin has been established. These multinuclear microparticles were made by polymerization in emulsion and characterized by scanning electron microscopy and interfacial tension measurements. This process is based on several emulsion mixings following Torza and Mason's approach, in which we combined the characteristics of a coacervation with a conventional interfacial reaction and an in situ polymerization followed by a water in oil in water emulsion. The inner phase of the microcapsules consisted of a mixture of paraffin and microspheres of poly(vinyl) alcohol/hydrated salt crosslinked by methylene diisocyanate. The encapsulation mechanism is based on the liquid/solid–liquid separation of methoxylolmelamines and will be described in this study to explain the surface morphology. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008