A simple and efficient synthesis of gem-dihydroperoxides from ketones using aqueous hydrogen peroxide and catalytic ceric ammonium nitrate
A simple and efficient synthesis of gem-dihydroperoxides from ketones using aqueous hydrogen peroxide and catalytic ceric ammonium nitrate
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DOI：
10.1016/j.tetlet.2007.07.012
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发表时间：
2007-09-03
影响因子：
1.8
通讯作者：
Ravikanth, Bommena
中科院分区：
文献类型：
--
作者：
Das, Biswanath;Krishnaiah, Maddeboina;Ravikanth, Bommena
室温下，在乙腈中加入适量的CaN，用50%的H_2O_2水溶液处理丙酮，可在较短的时间内高产率地将酮转化为相应的宝石二氢氧化物。(C)2007爱思唯尔有限公司。保留所有权利。
Ketones were efficiently converted into the corresponding gem-dihydroperoxides in high yields within a short period of time on treatment with aqueous H2O2 (50%) in the presence of a catalytic amount of CAN in acetonitrile at room temperature. (c) 2007 Elsevier Ltd. All rights reserved.