PULSED LASER ASSISTED REACTIONS OF B AND N ATOMS IN A CONDENSING NITROGEN STREAM
PULSED LASER ASSISTED REACTIONS OF B AND N ATOMS IN A CONDENSING NITROGEN STREAM
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DOI：
10.1021/j100202a020
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发表时间：
1992-11-12
影响因子：
--
通讯作者：
ANDREWS, L
中科院分区：
文献类型：
--
作者：
HASSANZADEH, P;ANDREWS, L
硼的脉冲激光蒸发和氮的离解提供了B和N原子用于在冷凝的氮流中反应。利用氮、硼混合同位素多重谱图对固体氮中的主要产物NNBN和次要产物NBN、BNN进行了鉴定。氮原子参与了这些反应，通过观察到的N3自由基和强烈的绿色辉光退火验证。潜在的活性氮基质降低了二硼物种的产率。
Pulsed laser evaporation of boron and dissociation of nitrogen have provided B and N atoms for reaction in a condensing nitrogen stream. The major product NNBN and the minor products NBN and BNN were identified by mixed nitrogen and boron isotopic multiplets from the FTIR spectra in solid nitrogen. Nitrogen atoms participate in these reactions as verified by the observation of N3 radical and an intense green glow on annealing. The yield of diboron species was reduced by the potentially reactive nitrogen matrix.